The concentration of H₃O⁺ ions in water is very low indeed at 10⁻⁷ mol dm⁻³. Pure water at 25 °C therefore has a pH of 7.00. Hydronium ions in pure water can arise only from water protonating (and deprotonating) itself. One molecule of water acts as a base, deprotonating another that acts as an acid. For every H₃O⁺ ion formed, a hydroxide ion must also be formed, so that in pure water at pH 7 the concentrations of H₃O⁺ and hydroxide ions must be equal: [H₃O+] = [HO⁻] = 10⁻⁷ mol dm⁻³.

The product of these two concentrations is known as the ionization constant (or as the ionic product) of water, KW, with a value of 10⁻¹⁴ mol² dm⁻⁶ (at 25 °C). This is a constant in aqueous solutions, so if we know the hydronium ion concentration (which we can get by measuring the pH), we also know the hydroxide concentration since the product of the two concentra-tions always equals 10⁻¹⁴. So, roughly at what pH does water become mostly H3O+ ions and at what pH mostly hydrox ide ions? We can now add two additional pieces of information to the approximate chart we gave you before. At pH 7, water is almost entirely H₂O. At about pH 0, the concentrations of water and H₃O⁺ ions are about the same and at about pH 14, the concentrations of hydroxide ions and water are about the same.

مواضيع ذات صلة

The definition of pKa

Water can behave as an acid or as a base

Every acid has a conjugate base

The pH scale and pKa

An isolated proton is extremely reactive—formation of H3O+ in water

Acids, bases, and pKa

Charged compounds can be separated by acid–base extraction

Organic compounds are more soluble in water as ions

Heterocyclic aromatic compounds

Hückel’s rule tells us if compounds are aromatic

Molecular orbitals and aromaticity

The π molecular orbitals of other conjugated cyclic hydrocarbons