The amount of H₃O⁺ in any solution in water is described using the pH scale. pH is simply a measure of the concentration of H₃O⁺ on a logarithmic scale, and it is characteristic of any aqueous acid—it depends not only on what the acid is (hydrochloric, acetic, etc.) but also on how concentrated the acid is.

●pH is the negative logarithm of the H₃O⁺ concentration. pH = –log[H₃O⁺]

You will already know that neutrality is pH 7 and that below pH 7 water is increasingly acidic while above pH 7 it is increasingly basic. At higher pH, there is little H3O+ in the solution and more hydroxide ion, but at lower pH there is more H3O+ and little hydroxide.

The reason that higher pH means less H₃O⁺ is because the arbitrary defi nition of pH is the negative logarithm (to the base 10) of the H₃O⁺ concentration. To summarize in a diagram:

pH is used to measure the acidity of aqueous solutions, but what about the inherent ten dency of an acidic compound to give up H⁺ to water and form these acid solutions? A good way of measuring this tendency is to find the pH at which a solution contains exactly the same amount of the protonated, acidic form and its deprotonated, basic form. This number, which is characteristic of any acid, is known as the pKa. In the example just above, this would be the pH where the amount of the carboxylic acid is matched by the amount of its carboxylate salt—which happens to be at about pH 5: the pKa of acetic acid is 4.76. We’ll come back to a more formal definition of pKa later, but first we need to look more closely at this pair of species—the protonated acid and its deprotonated, basic partner.

مواضيع ذات صلة

The definition of pKa

The ionization of water

Water can behave as an acid or as a base

Every acid has a conjugate base

An isolated proton is extremely reactive—formation of H3O+ in water

Acids, bases, and pKa

Charged compounds can be separated by acid–base extraction

Organic compounds are more soluble in water as ions

Heterocyclic aromatic compounds

Hückel’s rule tells us if compounds are aromatic

Molecular orbitals and aromaticity

The π molecular orbitals of other conjugated cyclic hydrocarbons